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Zinc (Zn) metal anode suffers from uncontrollable Zn dendrites and parasitic side reactions at the interface, which restrict the practical application of aqueous rechargeable zinc batteries (ARZBs). Herein, an amphoteric cellulose-based double-network is introduced as hydrogel electrolyte to overcome these obstacles.

The construction of a robust solid–electrolyte interphase (SEI) on zinc anode is an effective approach for tackling the high thermodynamic instability and side reactions of Zn-metal anode (ZMA), particularly at high current densities and high utilization ratios. Herein, a ternary aqueous electrolyte with N,N

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